Brush for applying substance to eyelashes and/or eyebrows

ABSTRACT

A brush for applying a substance onto keratinous fibers includes a core and bristles that are supported by the core and made other than by being injection molded together with the core. In embodiments, the brush has at least a portion that carries bristles that are curved and extend from the core in oriented manner.

[0001] The present invention relates to applicators for applying a substance to keratinous fibers, in particular the eyelashes or the eyebrows, and it relates more particularly but not exclusively to mascara brushes.

[0002] U.S. Pat. No. 4,561,456 describes a brush made by injection molding a plastics material to have bristles that present ends that are hook-shaped. A drawback of such a brush is that it requires a special mold to make it. In addition, the way the bristles are implanted is rather different from a conventional brush with a twisted core.

[0003] There exists a need to benefit from an improved brush which is relatively easy to manufacture while also being capable of applying makeup in satisfactory manner.

[0004] In a first aspect amongst others, the invention provides a brush for applying a substance onto keratinous fibers, the brush comprising:

[0005] a core; and

[0006] bristles supported by the core and made other than by being injection molded together with the core;

[0007] the brush including at least one portion having bristles that are curved so as to extend from the core in an oriented manner.

[0008] The term “extend in oriented manner” is used to mean that the curved bristles extend with a general orientation that is defined during manufacture of the brush and not with an orientation that is completely random.

[0009] The brush may be of any type having bristles fitted to its core.

[0010] A brush of the invention presents advantages associated with the curvature of the bristles, while also being suitable for being manufactured with a conventional twisted core, for example, thus making it possible to provide brushes having a variety of implantations, seeking to obtain various makeup effects, without requiring special and expensive molds to be made. In addition, a brush of the invention is suitable for retaining a relatively large quantity of substance, thus making it possible to coat eyelashes thoroughly.

[0011] The brush may include at least a portion with curved bristles oriented in the same circumferential direction about the core.

[0012] When the core is twisted, it may be twisted to the left, i.e. the branches of the core form spirals which rise going from left to right, when the brush is observed while in the vertical position with its end that is fixed in the stem, i.e. its proximal end, situated at the bottom and its free end, i.e. its distal end, situated at the top. For a left twisted brush, the bristles may be oriented in the clockwise direction, when the brush is observed on its axis from its distal end towards its proximal end. In a variant, the bristles may be oriented in the counterclockwise direction. Concerning the advantages that result from having a core which is twisted to the left, reference may usefully be made to U.S. Pat. No. 6,227,735. The fact of imparting curvature, in the manner described above, to the bristles of a brush with a core that is twisted to the left makes it possible to further improve the way eyelashes are taken in charge, and to further improve the application of makeup.

[0013] The invention also applies to brushes with a core twisted to the right, and to brushes with a core that is not twisted, with the bristles being fixed by being punched into the core, for example, as described in European patent application No. EP-A-1 155 637, or indeed fixed by being stapled to the core.

[0014] The brush may include at least a portion carrying curved bristles that are generally oriented in the same axial direction, e.g. towards the proximal end or towards the distal end of the brush, and where appropriate it may have bristles oriented “obliquely” both in a given circumferential direction and in a given axial direction.

[0015] The portion of the brush that includes curved bristles extending from the core in oriented manner may, in the limit, correspond to the entire brush. However, this portion need not correspond to the entire brush, and by way of example it may correspond merely to a portion extending from one end of the brush and over less than half the length thereof, for example, or to special regions of the brush, e.g. regions defining peaks or notches.

[0016] At least 20% of the bristles of a brush may be curved, or at least 50%, e.g. at least 80%, and it is even possible for substantially all of the bristles of the brush to be curved.

[0017] The brush may include five to 60 bristles per turn, for example. The number of bristles per turn corresponds to the number of bristle ends counted by a stationary observer while the brush is being turned through 180° about its core.

[0018] The bristles may be made of synthetic material, e.g. being made out of a thermoplastic material.

[0019] The bristles may present a section that is solid or hollow, optionally circular, the cross-section of the bristles being constant or otherwise along their length, e.g. passing alternately through sections of large diameter and sections of small diameter, the bristles possibly carrying a coating of flocking.

[0020] The bristles may also include a filler, e.g. of a magnetic compound, a moisture-absorbing compound, a compound for imparting roughness to the surface of the bristle, or indeed a compound for improving sliding of the bristles over the eyelashes.

[0021] Bristle diameter may lie in the range {fraction (5/100)} millimeters (mm) to {fraction (35/100)} mm. The term bristle “diameter” is used to designate the diameter of the circle circumscribing the largest cross-section of the bristle, if the bristle is not itself circular.

[0022] The length of the bristles may lie in the range 1 mm to 7 mm, for example, and in particular in the range 2 mm to 5 mm.

[0023] The brush may comprise a mixture of bristles of different lengths, or even of different kinds.

[0024] By way of example, only the longest bristles of the brush may be curved in shape, with the others extending in rectilinear manner from the core.

[0025] When the brush includes a mixture of bristles of different kinds, only bristles of a certain kind need be curved, for example. The brush may include, in particular, bristles made of materials having different vitreous transition temperatures, and only those bristles that are made of the material having the lowest vitreous transition temperature may be curved.

[0026] The envelope surface of the brush may present a variety of shapes, and in particular cross-sections that are circular, oval, polygonal, or other, having one or more indentations or notches.

[0027] The core may optionally be centered in a cross-section of the envelope surface.

[0028] The cross-section of the envelope surface may be constant over at least a portion of the length of the brush, or otherwise, and the brush may, for example, present a cross-section passing through an extremum between its two axial ends, which extremum may be a maximum or a minimum, for example. The brush may thus present, when seen from the side, a shape that is generally hourglass-shaped or (American) football-shaped.

[0029] The core may optionally be rectilinear, and in particular it may be curved, with curvature distributed over its length or localized only in a region close to the region used for fixing the brush to an applicator stem.

[0030] Where appropriate, the brush may be curved about at least two axes that are not coplanar.

[0031] Another object of the invention is to provide a packaging and applicator device including such a brush.

[0032] In another of its aspects, the invention also provides a method of manufacturing a brush for applying a substance onto keratinous fibers, in particular the eyelashes or the eyebrows, the method including the following steps:

[0033] curving the bristles of the brush by bringing them into contact with a hot surface, in particular a surface that is moving relative to the brush.

[0034] The surface is preferably defined by a material presenting relatively low thermal conductivity, such as, for example: a silicone, a fluorine-containing polymer, in particular polytetrafluoroethylene (PTFE), or an inorganic material other than a metal, e.g. graphite. The use of a material presenting relatively low thermal conductivity makes it possible to prevent the bristles sticking to the hot surface while the brush is being treated, and also makes it possible to avoid melting the ends of the bristles or even welding them together.

[0035] The relative movement between the brush and the hot surface may be selected as a function of the general orientation it is desired to impart to the bristles.

[0036] In a particular implementation of the invention, the brush is rotated about its axis, thereby enabling at least one longitudinal portion of the brush to be treated over its entire circumference.

[0037] The hot surface may be defined by a stationary treatment member or a treatment member that is moved axially during the treatment, e.g. in one direction only or with reciprocating motion.

[0038] Movement in a single axial direction can serve to orient the bristles towards the proximal end or towards the distal end of the brush, for example.

[0039] Rotating the brush serves, for example, to orient the bristles in a common circumferential direction, which may be selected as a function of the orientation of the turns of the core, in particular when the brush is a twisted-core brush.

[0040] In a particular implementation of the invention, the treatment member is caused to rotate, with the brush being stationary or likewise caused to rotate, e.g. in the same direction of rotation or in a direction of rotation opposite to that of the treatment member. The brush may also be displaced axially relative to the treatment member.

[0041] The hot surface may present a variety of shapes depending on the treatment that is to be performed.

[0042] In particular, the hot surface may present a shape causing the brush to bear over a single sector of its circumference, or to bear against two separate sectors of its circumference, as applies for example when the hot surface is in the form of two planes intersecting at a dihedral angle that is small enough for the bristles of the brush not to reach the intersection.

[0043] The surface state of the treatment member may be selected as a function of the treatment that it is desired to perform. Thus, the hot surface may be smooth or it may be slightly rough, for example.

[0044] In another of its aspects, the invention also provides a machine for manufacturing a brush for applying a substance onto keratinous fibers, said machine being suitable for implementing the above-defined method, said machine comprising:

[0045] a support arranged to support at least one brush; and

[0046] a treatment member for treating at least said brush and comprising:

[0047] a surface arranged to come into contact with the bristles of the brush;

[0048] heater means for heating said surface; and

[0049] means for imparting relative displacement between the support and the treatment member so as to modify, in predefined manner, the orientation of the bristles of the brush that come into contact with the surface of the treatment member.

[0050] By way of example, the drive means may comprise at least one motor for rotating the brush about its own axis and/or for driving the treatment member in rotation, and where appropriate for driving the brush and/or the treatment member in axial displacement. The drive means may also serve to move the brush and the hot surface of the treatment member towards each other or apart from each other. The brush and the treatment member may be driven simultaneously to rotate about axes that are parallel or not parallel.

[0051] When the brush includes a twisted core, in particular a core twisted to the left, the brush may be rotated about its axis in a direction that is seen as counterclockwise when the brush is observed end-on from its distal end. This causes the bristles to be oriented in the circumferential direction which is favorable to the bristles of the brush taking proper charge of the eyelashes.

[0052] The temperature to which the surface of the treatment member for coming into contact with the bristles of the brush is heated depends on the nature of the bristles of the brush and on the treatment that is to be imparted to the bristles. By way of example, this temperature may lie in the range 80° C. to 220° C., and is preferably greater than or equal to about 150° C., in particular when the bristles of the brush are made of polyamide 6/6, 6/10, 6/12, or 11.

[0053] When the brush is rotated, the speed at which it is rotated may lie in the range 100 revolutions per minute (rpm) to 1200 rpm. This speed may be selected as a function specifically of the temperature of the treatment member, the contact pressure between the bristles and the treatment member, and the shape of the treatment member.

[0054] The invention can be better understood on reading the following detailed description of non-limiting embodiments thereof, and on examining the accompanying drawings, in which:

[0055]FIG. 1 is a diagrammatic axial section view of a packaging and applicator device including a brush of the invention;

[0056]FIG. 2 is a view of the FIG. 1 brush as seen along arrow II, constituting a highly diagrammatic face view of the distal end of the brush;

[0057]FIG. 3 is a diagrammatic and fragmentary view showing bristles held between the twisted branches of the core of the FIG. 1 brush;

[0058]FIG. 4 is a diagrammatic view for showing an example of the treatment to which the brush may be subjected;

[0059]FIG. 5 is a cross-section of the treatment member of FIG. 4;

[0060]FIG. 6 shows a variant of the treatment member;

[0061]FIG. 7 shows how it is possible to treat only a portion of the length of the brush;

[0062]FIGS. 8, 9, and 9A show variant treatment members;

[0063] FIGS. 10 to 12 show various shapes of bristle that can be obtained, amongst others;

[0064]FIG. 13 shows how it is possible to treat only an angular sector of the brush;

[0065]FIGS. 13A and 13B show how at least two angular sectors of the brush can be treated differently;

[0066]FIG. 14 is a diagrammatic cross-section view of a brush having short bristles that are rectilinear and long bristles that are curved;

[0067]FIG. 15 is a diagram showing a brush envelope that is substantially triangular in cross-section;

[0068]FIG. 16 is a highly diagrammatic face view of the distal end of a brush whose envelope presents substantially a cross-section corresponding to that of FIG. 15;

[0069]FIG. 17 is a diagram of a brush envelope that is generally square in cross-section;

[0070]FIG. 18 is a highly diagrammatic face view of the distal end of a brush whose envelope presents substantially the cross-section shown in FIG. 17;

[0071] FIGS. 19 to 26 are diagrammatic cross-section views of other possible shapes for the brush envelope;

[0072]FIG. 27 shows how the core may be off-center;

[0073]FIGS. 28 and 29 are diagrammatic side views showing brush envelopes of cross-section that is not constant;

[0074]FIG. 30 is a diagram of the FIG. 29 brush after its core has been curved;

[0075]FIG. 31 shows another example of a curved-core brush;

[0076]FIG. 32 is a view analogous to FIG. 3 showing a portion of a brush core that is twisted to the right;

[0077]FIG. 33 is a view analogous to FIG. 3 showing a portion of a brush in which the bristles are curved both circumferentially and axially;

[0078] FIGS. 34 to 51 show various examples amongst others of cross-sections that can be used for the bristles;

[0079] FIGS. 52 to 55 show end portions of the bristles; and

[0080]FIG. 56 is a diagrammatic view of a pair of cores, with the bristles being omitted.

[0081] The packaging and applicator device 1 shown in FIG. 1 comprises a receptacle 2 containing a substance P for applying to the eyelashes or the eyebrows, e.g. mascara, and an applicator 3 comprising a stem 4 having a longitudinal axis X and provided at one end 4 a with a brush 5 and at its opposite end with a handle member 6 that also serves to close the receptacle 2. The receptacle has a neck 7 with an outside thread so as to enable the handle member 6 to be screwed thereon.

[0082] A wiper member 8 is fixed inside the neck 7 for wiping the stem 4 and the brush 5 while they are being taken out of the receptacle. The wiper member 8 has a flexible lip 9 defining a circular orifice of diameter corresponding substantially to the diameter of the stem 4.

[0083] Naturally, the invention is not limited to using a particular wiper member, and other wiper members may also be used, e.g. wiper members comprising a block of foam and/or defining one or more slots, which may optionally be flocked.

[0084] In the example shown, the stem 4 is rectilinear, however it could be curved without thereby going beyond the ambit of the present invention.

[0085] In addition, the stem 4 is shown as being fixed relative to the handle member 3, however it could be movable relative thereto, e.g. by means of an articulated connection, in particular one including a ball-and-socket joint.

[0086] The brush 5 includes a core 10 made up of two twisted-together metal strands, the core 10 being fixed at one end in a socket in the stem 4, e.g. being a force-fit in said socket.

[0087] The brush 5 also has bristles 3 which are held in place by being clamped between the twisted-together strands of the core 10, as can be seen in FIGS. 2 and 3. In FIG. 3, the core is shown as seen in side view with the proximal end of the brush being on the left of the figure and its distal end being on the right, the brush shown being said to be “twisted to the left”.

[0088] In accordance with an aspect of the invention, the brush 5 includes at least one portion having bristles that are not rectilinear, being curved in shape as can be seen in FIG. 2, in particular. In the example described, the bristles 11 are generally curved in the same circumferential direction, i.e. counterclockwise in FIG. 2.

[0089] In order to make the brush of FIGS. 1 to 3, the brush can be brought into contact (as shown in FIG. 4) with a treatment member 20 comprising a surface 21 which can be touched by the bristles of the brush.

[0090] By way of example, it is possible to start with a brush of envelope surface that is circularly cylindrical about an axis Y, which may coincide with the above-mentioned axis X, and then to rotate the brush about said axis Y while it is in contact with the surface 21. The radius of curvature of the surface 21 may correspond substantially to the radius of the envelope surface of the brush so that contact between the brush 5 and the treatment member 20 takes place over an angular sector of the brush.

[0091] In the example of FIG. 4, the treatment member 20 extends parallel to the axis Y over at least the entire length of the brush.

[0092] In order to obtain bristle curvature as shown in FIG. 2, the brush is rotated, for example, about the axis Y in the direction that is seen as being clockwise when the brush is observed along its axis Y with the distal end 5 a of the brush in front, as shown in FIG. 4.

[0093] The treatment member 20 has heater means 22, e.g. an electrical resistance element or a duct for circulating a heat-conveying fluid, thereby enabling the surface 21 to be raised to a temperature which is sufficient to lead to permanent deformation of the bristles 11 of the brush after the bristles have been brought into contact with the treatment member 20.

[0094] By way of example, the surface 21 may be raised to a temperature of about 150° C. for a brush comprising bristles made of polyamide, in particular polyamide 6/6.

[0095] By way of example, the brush is rotated at a speed of about 1000 rpm if it has polyamide bristles, and in particular bristles made of polyamide 6/6, with the surface 21 being at a temperature of about 150° C., by means of a support 30 coupled to a motor and including a jaw 31 for taking hold of the core of the brush.

[0096] The treatment member 20 comprises a body 23 defining the surface 21, which body is made of a material that presents relatively poor thermal conductivity, e.g. silicone, thus making it easier for the bristles coming into contact with the surface 21 to avoid sticking thereto, and in particular to ensure that the ends of the bristles do not melt and become welded together. Alternatively, only a surface coating on the treatment member need be made out of such a material.

[0097]FIGS. 6 and 7 show how the treatment member 20 need not extend over the full length of the brush, for example in order to treat only a portion l′ or l″ thereof, the portions l′ and l″, respectively extending from the distal end and the proximal end of the brush, each over about half the total length of the brush.

[0098]FIG. 6 also shows that it is possible to impart relative movement along the Y axis of the brush between the brush and the treatment member 20, e.g. for the purpose of pointing the bristles towards the proximal end or towards the distal end in addition to possibly orienting the bristles in the circumferential direction.

[0099]FIG. 8 shows that it is possible for the treatment member 20 to present a surface 21 whose radius of curvature is greater than the radius of curvature of the cylindrical envelope of the brush, for example. Depending on the radius of curvature of the surface 21, it will be understood that it is possible to act on the contact time between the bristles of the brush and the surface 21 for given speed of rotation of the brush about its axis Y.

[0100] The surface 21 may present a variety of shapes, and for example its shape need not be circularly cylindrical, as shown in FIG. 9.

[0101] In this figure, the surface 21 comprises two plane portions 21 a and 21 b intersecting at a dihedral angle, with the bristles of the brush 5 being capable of coming into contact with said portions 21 a and 21 b, while bristles of the brush that are situated between these portions 21 a and 21 b do not come into contact with the surface 21.

[0102] Where appropriate, and as shown in FIG. 9A, the treatment member 20 may comprise at least two separate portions 20 a and 20 b defining respective hot surfaces 21 a and 21 b with which the bristles of the brush can come into contact.

[0103] Depending on the duration of contact with the heated surface 21, and in particular depending on the speed of rotation of the brush, the contact pressure of the bristles against said surface 21, the friction forces between the bristles and the surface 21, and also the nature of the bristles of the brush, it is possible for the initial rectilinear shape of the bristles to be modified to a greater or lesser extent, in particular for the purpose of obtaining shapes that are curved to a greater or lesser extent, as shown in FIGS. 10 to 12.

[0104] In the examples of FIGS. 4, 6, 8, 9, and 9A, the brush may be rotated about the axis Y and the treatment member 20 need not be rotary.

[0105] In a variant, it is the treatment member 20 that may be rotated while the brush 5 is kept stationary, thereby making it possible to treat a fraction only of the circumference of the brush, which brush may thus present a first set s′ of bristles that are curved over a portion of its circumference, and a second set s″ of bristles that are rectilinear over the remainder of its surface (as shown in FIG. 13).

[0106] It is also possible, for example, to treat the bristles in a certain manner over a sector s′ of the circumference of the brush and in another manner over a different sector s″. For example, it is possible to treat the bristles over the sector s′ in such a manner as to orient them clockwise, and to treat them over the sector s″ in such a manner as to orient them in the opposite direction.

[0107] For a brush of envelope presenting a cross-section that is not circular in shape, it is possible, for example, to treat the different sides of the brush differently. For example, for the brush shown in FIG. 13B, it is possible to treat the sides of the brush in such a manner as to orient all of the bristles on one side in a given direction, with the direction in which the bristles are oriented reversing on moving from one side to the following side.

[0108] The brush may be made out of a mixture of long bristles 11 a and short bristles 11 b and it may be treated in such a manner that only the long bristles 11 a come into contact with the heated surface 21 so as to take on a curved shape, the short bristles 11 b not being heated and remaining rectilinear, as shown in FIG. 14.

[0109] The brush may present an envelope surface as defined by the free ends of the bristles that is non-circular in section.

[0110] By way of example, FIG. 15 shows an envelope surface of cross-section that is substantially prismatic, e.g. substantially triangular. With such a brush, by causing the brush to turn about its axis Y in contact with a heated surface, it is possible to obtain bristles having a curved shape, e.g. in the counterclockwise direction, as shown in FIG. 16.

[0111]FIG. 17 shows an envelope surface of cross-section that is substantially square.

[0112] With such a brush, it is possible, for example, to obtain a curved shape for the bristles as shown in FIG. 18, with the bristles being oriented, for example, in the counterclockwise direction as can be seen in the figure.

[0113] FIGS. 19 to 26 show further possible shapes, amongst others, for the cross-sections of the envelope surface of the brush.

[0114]FIG. 19 thus shows a cross-section of substantially pentagonal shape and FIG. 20 shows a shape that is substantially hexagonal.

[0115]FIG. 21 shows a cross-section that is substantially oval in shape.

[0116]FIG. 22 shows that it is possible to make the brush with at least one indentation 41, which may be concave towards the outside as shown, said indentation presenting a cross-section that is constant or otherwise on moving along the brush.

[0117]FIG. 23 shows that it is possible to make, on the brush, at least one facet 42 that is substantially plane.

[0118]FIG. 24 shows that it is possible to make the brush with at least one notch 43, and specifically with three notches.

[0119]FIG. 25 shows a variant embodiment of a brush having two notches 43 and FIG. 26 corresponds to a variant embodiment that has only one.

[0120] The core 10 may optionally be centered relative to the outline of the envelope surface, when the brush is observed in cross-section.

[0121] By way of illustration, FIG. 27 shows a brush whose core is off-center.

[0122] The cross-section of the brush may be constant or otherwise, and its core may be rectilinear or otherwise.

[0123] When the core is rectilinear, either because the final brush presents a rectilinear core or because the core has been straightened out and made rectilinear for observation purposes, the brush may present a cross-section that passes through an extremum 45, as shown in FIG. 27, which extremum may be a maximum or a minimum. FIG. 18, with the bristles being oriented, for example, in the counterclockwise direction as can be seen in the figure.

[0124] FIGS. 19 to 26 show further possible shapes, amongst others, for the cross-sections of the envelope surface of the brush.

[0125]FIG. 19 thus shows a cross-section of substantially pentagonal shape and FIG. 20 shows a shape that is substantially hexagonal.

[0126]FIG. 21 shows a cross-section that is substantially oval in shape.

[0127]FIG. 22 shows that it is possible to make the brush with at least one indentation 41, which may be concave towards the outside as shown, said indentation presenting a cross-section that is constant or otherwise on moving along the brush.

[0128]FIG. 23 shows that it is possible to make, on the brush, at least one facet 42 that is substantially plane.

[0129]FIG. 24 shows that it is possible to make the brush with at least one notch 43, and specifically with three notches.

[0130]FIG. 25 shows a variant embodiment of a brush having two notches 43 and FIG. 26 corresponds to a variant embodiment that has only one.

[0131] The core 10 may optionally be centered relative to the outline of the envelope surface, when the brush is observed in cross-section.

[0132] By way of illustration, FIG. 27 shows a brush whose core is off-center.

[0133] The cross-section of the brush may be constant or otherwise, and its core may be rectilinear or otherwise.

[0134] When the core is rectilinear, either because the final brush presents a rectilinear core or because the core has been straightened out and made rectilinear for observation purposes, the brush may present a cross-section that passes through an extremum 45, as shown in FIG. 28, which extremum may be a maximum or a minimum.

[0135] As shown in FIG. 29, the cross-section of the brush may pass through both a maximum 46 and a minimum 47.

[0136] The core may be curved, e.g. so as to straighten out one edge 48 of the brush, as shown in FIGS. 29 and 30.

[0137] The brush 5 may also have a core that includes a bend 49 close to the distal end 4 a of the brush 4, as shown in FIG. 31, with the portion of the core that carries the bristles possibly being rectilinear.

[0138] In all of the above examples, the brush may also be twisted to the right, as shown in FIG. 32.

[0139]FIG. 33 shows bristles oriented both in the circumferential direction and in the axial direction, in the direction of the arrow in said figure.

[0140] The bristles used may present a variety of cross-sections, other than being circular in cross-section.

[0141] In particular, it is possible to use bristles presenting a cross-section having any of the shapes shown diagrammatically in FIGS. 34 to 51, e.g. a circular shape with a flat as shown in FIG. 34, a flat shape as shown in FIG. 35, a star shape, e.g. in the form of a cross as shown in FIG. 36 or having three branches as shown in FIG. 37, a U-shape as shown in FIG. 38, an H-shape as shown in FIG. 39, a T-shape as shown in FIG. 40, a V-shape as shown in FIG. 41, a hollow shape, e.g. a circular hollow shape as shown in FIG. 42 or a prismatic and in particular a square hollow shape as shown in FIG. 43, a shape forming ramifications, e.g. in the form of a snowflake as shown in FIG. 44, a section that is polygonal, e.g. triangular as shown in FIG. 45, square as shown in FIG. 46, or hexagonal as shown in FIG. 47, or an oblong shape, in particular a lens shape as shown in FIG. 48 or an hourglass shape as shown in FIG. 49.

[0142] It is also possible to use bristles including portions that are hinged to one another as shown in FIG. 50. It is also possible to use bristles presenting at least one capillary groove 60 as shown in FIG. 51. Where appropriate, prior to being curved, the bristles may be subjected to treatment for forming beads 61 at their ends, as shown in FIG. 52, or forks 62 as shown in FIG. 53.

[0143] It is also possible to use flock-covered bristles as shown in FIG. 54, or bristles made by extruding a plastics material that contains a filler of particles 63 in order to confer microrelief to the surface of the bristles as shown in FIG. 54 or in order to impart magnetic or other properties thereto.

[0144] The bristles may also be made of a material presenting properties that encourage sliding.

[0145] The bristles may be made of synthetic materials selected, for example, from polyethylene, polyamides and in particular PA6, PA6/6, PA6/10, PA6/12, or PA11, in particular Rilsan®, a Hytrel®-Pebax® polymer, and other thermoplastic polymers.

[0146] Naturally, the invention is not limited to the examples described above.

[0147] It is possible in particular to make the core differently, for example by using a pair of cores made up of two individual cores 10′ and 10″ that are twisted around each other as shown in FIG. 56. Each of the individual cores 10′, 10″ in this figure itself comprises two twisted-together strands that hold bristles.

[0148] To make the core, it is possible to use metal strands of optionally circular section, which strands may optionally be sheathed.

[0149] The characteristics of the various embodiments described above can be combined with one another.

[0150] Throughout the description, including in the claims, the term “comprising a” should be understood as being synonymous with “comprising at least one”, unless specified to the contrary. 

1. A brush (5) for applying a substance onto keratinous fibers, the brush comprising: a core (10); and bristles (11) supported by the core and made other than by being injection molded together with the core; the brush including at least one portion having bristles that are curved so as to extend from the core in an oriented manner.
 2. A brush according to claim 1, characterized by the fact that it includes at least portion comprising curved bristles that are generally oriented in the same circumferential direction about the core.
 3. A brush according to the preceding claim, characterized by the fact that the core is twisted to the left.
 4. A brush according to claim 3, characterized by the fact that the bristles are oriented in the clockwise direction when the brush is observed along its axis from its distal end towards its proximal end.
 5. A brush according to claim 3, characterized by the fact that the bristles are oriented in the counterclockwise direction when the brush is observed along its axis from its distal end towards its proximal end.
 6. A brush according to any preceding claim, characterized by the fact that the brush includes at least one portion carrying curved bristles that are oriented generally in the same axial direction.
 7. A brush according to any preceding claim, characterized by the fact that at least 20% of its bristles are curved, or at least 50%, and in particular at least 80%.
 8. A brush according to any preceding claim, characterized by the fact that it carries five to 60 bristles per turn.
 9. A brush according to any preceding claim, characterized by the fact that the bristles are made of a thermoplastic material.
 10. A brush according to any preceding claim, characterized by the fact that the diameter of the bristles lies in the range {fraction (5/100)} mm to {fraction (35/100)} mm.
 11. A brush according to any preceding claim, characterized by the fact that the bristles are of a length lying in the range 1 mm to 7 mm, and in particular in the range 2 mm to 5 mm.
 12. A brush according to any preceding claim, characterized by the fact that it carries a mixture of bristles of different lengths.
 13. A brush according to any preceding claim, characterized by the fact that it carries bristles of kinds that are different.
 14. A brush according to claim 11, characterized by the fact that only the longest bristles of the brush present a shape that is curved, the other bristles extending from the core in rectilinear manner.
 15. A brush according to claim 13, characterized by the fact that it carries bristles made of materials having vitreous transition temperatures that are different, with only those bristles that are made of the material having the lowest vitreous transition temperature being curved.
 16. A method of manufacturing a brush for applying a substance onto keratinous fibers, in particular the eyelashes or the eyebrows, the method including the following step: curving the bristles of the brush by putting them into contact with a hot surface, in particular a surface that is moving relative to the brush.
 17. A method according to the preceding claim, characterized by the fact that the surface (21) is preferably defined by a material presenting relatively low thermal conductivity, in particular a silicone, a fluorine-containing polymer, in particular a polytetrafluoroethylene, or an inorganic material other than a metal, in particular graphite.
 18. A method according to claim 16 or claim 17, characterized by the fact that the brush is rotated about its own axis (Y).
 19. A method according to any one of claims 16 to 18, characterized by the fact that the hot surface (21) is defined by a treatment member (20).
 20. A method according to claim 19, characterized by the fact that the treatment member (20) is rotated, the brush being held stationary.
 21. A method according to any one of claims 16 to 20, characterized by the fact that the hot surface (21) is moved axially during treatment.
 22. A machine for manufacturing a brush for applying a substance onto keratinous fibers, said machine serving to implement the method defined in any one of claims 16 to 21, the machine comprising: a support (30, 31) arranged to support at least one brush (5); and a treatment member (20) for treating at least said brush and comprising: a surface (21) arranged to come into contact with the bristles of the brush; heater means (22) for heating said surface; and means for imparting relative displacement between the support and the treatment member so as to modify, in predefined manner, the orientation of the bristles of the brush that come into contact with the surface (21) of the treatment member (20). 